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People often argue about fly ash, and why we should or shouldn’t use it in concrete and other building products. (More about what fly ash actually is follows below.) It’s a bit of a hot topic in green building, and made for a lively but truncated group discussion at the recent Build Well 2010 Symposium near San Francisco. For that alone it makes a worthy topic with which to launch this Build Well Forum. As it turns out, it is also worth discussing because the issue is emblematic of two important, overarching green building issues that don’t get enough attention:


1) Industrial Ecology
If we’re going to make good use of all the stuff we’ve been throwing away—the plastic in oceans and landfills, the metals and tires in municipal dumps, the by-products of industry and agriculture—then we’re probably going to do it in the built environment. The construction industry uses more physical stuff, by an order of magnitude and by any measure, than any other industry. Rather than continue to scrape virgin resources out of ever more undisturbed landscapes, we will have to learn to use what others throw away. What if we as a society were to craft policy that truly encouraged beneficial, and careful, reuse of “waste” material in the built environment? What if (for example), in fostering better building, rather than award dinky green points for often dubious recycled content, we were to penalize product manufacturers for use of virgin resources?

2) Transparency
No secrets! We want to know what’s in our food, what’s in our clothing, and what’s in our shelter. For several generations now we’ve been adding ingredients to everything we eat, wear and build with, giving little or no consideration to what effects those ingredients might have on our children, our bodies, and the planet that supports us. Increasingly, consumers want to know exactly what they’re buying, where it came from, and what trail it left. And yet . . . in some way we also have to protect intellectual property, and the keeping of trade secrets, because failure to do so puts a fast end to innovation. And innovation will surely be key to working our way out of the various jams we’re in.

All of which brings us back to fly ash, and its use in buildings.

I’ve been studying fly ash, and the industries around the issue, for 15 years now, and hope to here offer a few comments of worth. I wrote a book on fly ash concrete five years ago, but am really no expert. Nor am I in the pay of the coal or ash industries; I’m just an engineer who hates waste and looks for elegant solutions to problems large and small (Disclosure: I am an unpaid advisor to CalStar Products, who make fly ash bricks and pavers). By no means is this post meant to declare some “answer”, but only to start a conversation that might unpack this very difficult subject. I do go on a bit, but that’s probably necessary: this isn’t a simple issue, and to oversimplify it—as is often done—is to miss larger, important considerations.

So, what is fly ash?
When you burn coal to make electricity, you get two things. You get a lot of thermal energy with which you then boil water which provides steam to drive turbines that generate the power that eventually shows up in your wall socket and enables you to read this. It’s a thrillingly inefficient way to power things, and is increasingly the method of choice in the world because what we got is a whole lot of coal, is what we got. There are no other large sources of energy on the horizon, with present technology, that would enable us to immediately ramp down coal usage. Like it or not, we’ll be burning a lot of coal for at least another generation. In North America, about half our electricity comes from burning coal.

The other thing you get from burning coal, as with a wood fire, is ash. Burn ten tons of coal, you’ll get about a ton of ash.

In North America the burning of coal for power generates about a half a cubic foot per person per year. That’s a bucket of ash in the name of every man, woman and child in America, every year. Whether we like it or not, we have to do something with it. You are producing the ash; what do you want to do with it?

Some of that ash falls to the bottom of the smokestack, and is thus called bottom ash. A lot of it—the finer, purer stuff— rises with the warm exhaust plume, and thus earns the name fly ash. There are basically three things that you can do with that flying ash. One: you can just let it fly away and scatter, where it will eventually settle onto the ground or be filtered by every air-breathing organism in the area. To see how well that plan works, visit any Chinese city, or just look at photos online; much of that dense, smoggy haze is fly ash floating in the air. (Fly ash particles are fine enough to remain airborne for a long time, but you do not want to breathe them.)

Or you can install collectors of one type or another on the smokestack and gather the ash at the source. Now you’ve got cleaner air and lots of fly ash-- but what to do with it? One solution is to dump it in artificial lined ponds. Big, big ponds. Ponds that sometimes burst their banks and flood downstream with unpleasant grey muck, as recently happened in Tennessee. The other thing to do with the ash—our third option—is to make concrete with it. Which is a pretty slick option, in that ash skillfully blended into concrete does several nice things at once:

  • it makes economical use of a waste product,
  • it makes better concrete, and in many ways,
  • it chemically binds the heavy metals in the ash (yes, there are all sorts of metals in ash; which exact amount varies with the coal source and type of burning),
  • and, best of all,
  • its use means you don’t need as much Portland cement to act as the glue binding the concrete together. And that’s a solid win because the production of Portland cement (baked and crushed limestone with a bit of clay) gives off a lot of carbon dioxide. The production of Portland cement worldwide alone generates between five and eight percent (depending on who you ask and how you measure) of anthropogenic CO2 emissions.

So, what’s not to like? We pour lots of concrete, and have lots of ash that can be beneficially used to make better concrete. So let’s do it, right? Let’s gather as much of the ash as possible and pour it into concrete.

Increasingly, we are doing just that. But, to put it mildly, things are not so simple. Here are the main issues of particular concern:

1) Mercury
Testing to date shows that the metals in fly ash chemically bind in a cement matrix in concrete; they are rendered harmless. Mercury, however, may be a different matter because it is unique among metals in being liquid (and potentially gaseous) at normal temperature and pressure. Many hold that just the possibility of mercury offgassing from fly ash concrete is reason enough to ban its use in schools, if not everywhere. Testing to date suggests that this is not an issue, but much more needs to be studied.

2) Other uses of ash and other coal by-products
From a physical point of view, fly ash is a very utilitarian material, and we’ve probably just begun to explore its value to industry and society. It is used as a stabilizer for clay soils, as a structural filler for some plastics, and as a component of sheetrock and other building products that do not also have cement. Thus, some wonder: what happens to all those heavy metals: are they in the dust? Are they getting into our bodies through air or direct contact? What will happen when it’s time to deconstruct a building with fly ash products: are they safe to handle or bury? We also use bottom ash for various purposes, and gypsum harvested from the flue gas to make sheetrock; what are the safety concerns there?

or the more simplified, overarching concerns that linger:

3) Isn’t fly ash just a hazardous material, period?
Even the guys who sell fly ash would tell you not to put this stuff on your pancakes; like most of the substances in the natural world, fly ash is not for consumption or respiration. Does that mean we (or rather, the EPA) should formally declare it a hazardous substance, thus ending any chance of beneficial reuse or recycling?

4) If we use a lot of ash in concrete, don’t we then encourage or justify the burning of coal for electricity?
Not even close. We use only a fraction of the ash produced in America or worldwide for any economical purpose, and the rest is a bit hard to access or use for a host of reasons.

Over the past several years I’ve had a great many conversations and arguments about ash with stakeholders from all over the spectrum: fly ash suppliers, concrete contractors, academics who study ash, and healthy building advocates who are very nervous about it, or flat out hate it. As is always the case with us crazy humans, opinions are perhaps sometimes based more in emotion than fact, but then some pretty important facts remain obscure because credible testing just hasn’t been done, we just don’t have the answers. Neither, however, do those who adamantly oppose the use of ash in buildings offer a viable alternative for disposal. “Hauling it off to a hazardous waste facility” usually ends up meaning “dump it on the next generation”—and into the soil and air of this generation.

A very complex matter, an urgent matter, and one with no easy resolution. We need to study and know so much more, but meanwhile that bucket of ash with “your name here” is being produced every year.


Tagged in: materials , Design , ash
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Director of Research and Development Advanced Geopolymer Technologies LLC
written by Jonathan Hampton, July 26, 2010
I do not agree that it has been shown that heavy metals are rendered benign when fly ash containing them is incorporated into portland cement based concrete.
Portland cement may encapsulate to some degree but it does not transform the chemistry of the heavy metals as do acid/base ceramic cements and geopolymers.
Given the final portland strata has both micro and macro capillary structure, this concern is even more acute.
I would be interested to see a TCLP leachate test verifying the portland is locking up heavy metals
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written by Bruce , July 26, 2010
Thanks for the comment, Jonathan. My statements about the safe binding of heavy metals in fly ash concrete are based mainly on "High Performance, High Volume Fly Ash Concrete" (2002, p.smilies/cool.gif, and on personal conversations with P. K. Mehta and others who have studied ash for decades.

You would do us a great service if you would provide a short exposition on the difference between fly ash and geopolymers, and on the differences in the reaction chemistry (allowing for the fact that most of us aren't chemists!)

cheers,

Bruce
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written by Jonathan Hampton, July 27, 2010
Maybe the following would be a helpful primer to this vast subject:
Sintered ceramics have been in use as structural products since the beginning of human culture. Archeological findings such as rudimentary tools produced over thousands of years tell us a great deal about the human culture of those times. Ceramics are also modern technological materials, especially in high temperature applications, and hence ceramic science is an active field of research even today. Sintering of these ceramics, however, is energy intensive and expensive, when large sizes are sintered, The alternative is chemical bonding.

Portland cement is such a alternative. Formed by chemical reactions, it is an inexpensive product and is used in large volumes. There is a wide gap between the attributes of ceramics and portland cement, however. Ceramics exhibit superior mechanical properties compared to portland cements. Ceramics are far more stable in acidic and high temperature environments, but cements are not. Thermal stability of cements is poor, while ceramics are refractory and are used in very high temperature, such as linings in furnaces. Cements are porous but ceramics can be made very dense.

The modern technologicsal needs of sructural materials are not fulfilled entirely by these two types of materials. There is also a need for materials that exhibit properties in between cement and sintered ceramics. That need can be met by Chemically Bonded Phosphate Ceramic matrix composites---materials that are produced like cements at ambient or at slightly elevated temperatures, but exhibit properties of ceramics. These composites are attractive for many structural applications, including architectural producs, oil-field drilling cements, road repair materials that set very fast and also in very cold environments, stabilization of radioactive and hazardous waste streams, and biomaterials.

CBPC marix composites are formed by incorporating a small amount of CBPC binder in a much greater amount of a second-phase material. These components are then mixed with water to form a slurry that will react and form the composite. Varying properties of the additive alters the composite so that one obtains a range of products wih tailored properties. For example,mechanical properties can be virtually doubled by adding fly ash to the mixture. Adding insulative particles such as ash,sawdust,or hollow microspheres of silica can reduce the thermal conductivity. The ability of CBPC's to bind a range of materials (extenders) and to form composites makes them promising for niche applications that cannot be fulfilled by conventional cement.
Ever increasing industrial activity is depleting natural resources worldwide, and at the same time, producing wastes that need disposal. Much of the solid waste that is produced is nonhazardous and can be recycled as CBPC structural products. For example, statics from 1986 reveal that more than 40 tons of waste per person was produced in the US. That number has risen dramatically since 1986. CBPC;s can incorporate much of this benign high volume waste into value added products. When benign waste streams, especially fly ash, are incorporated in CBPC's at high loadings, the mechanical properties of CBPC's are enhanced several fold. Conventional cement does not have this advanagious property. While CBPC"s cost more than conventional cements, the fact one can utilize these kinds of fillers reduces the cost and makes CBPC's cost effective even when only initial cost is the criteria.


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written by Jonathan Hampton, July 27, 2010
Ceramics and hydraulic cements are two major classes of inorganic solids that are manmade and in common use. Ceramics are traditionally formed by compaction of powders and subsequent fusion at high to very high temperatures, ranging anywhere from around 700 to 2000 degrees C. Once fused, the resulting ceramics are hard and dense, and exhibit very good corrosion resistance. These materials have found applications in bricks, pottery, refractory products of zirconia,alumina,magnesia and high temperature superconductors. There are porous ceramics such as filters and membranes that are also fabricated by the sintering process, but porosity is introduced into them intentionally. Ceramics, in general, are highly crystalline with some glassy phase. If glassy phase dominates, then they are called "glass-ceramics".

Hydraulic cements are another class of technologically important materials. Examples include portland cements, calcium aluminate cements and plaster of Paris. They harden at room temperature when their powders are mixed with water. The pastes formed this way set into a hard mass that has sufficient compression strength and can be used as structural materials. Their structure is generally noncrystalline.

Hydraulic cements are excellent examples of accelerated chemical bonding. Hydrogen bonds are formed in these materials by chemical reaction when water is added to the powders. These bonds are distinct from the bonds in ceramics in which high temperature interparticle diffusion leads to consolidation of powders.

Portland cement is the most common hydraulic cement. It is not the only one. It is formed by clinkering a mixture of powders of limestone, sand, iron oxide and other additives at a very high temperature (about 1500 C ) It is mixed with water to form hydrated bonding phases of dicalcium and tricalcium silicates (Ca2SiO4 and Ca3SiO5), dicalcium aluminate (Ca2Al2O6), and calcium aluminoferrite (Ca4(Fe1-xAlx)O5). When this cement is mixed with sand and gravel (must be clean) in bonds to them to form cement concrete that is used in construction. Typically initial bonding occurs in a few hours, but slow curing takes place for weeks or even months to gain full strength.

The preparation of calcium aluminate cements is similar. Here, instead of calcium and silica, calcium and alumina ract with water to form hydrated calcium aluminate as the bonding phase. The initial strength gain for this material is faster than that for portland cement.

Intense research in hydraulic cements has resulted in a wide range of blends that are used in a wide range of applications. Accelerated setting formulations have been developed to gain high early strengths. Reducers of water demand have been used to develop macro-defect-free (MDF) cements in which large size pores are eliminated. Pumpable versions of portland cement for oil drilling applications are common. All the modifications however, depend on the primary bonds formed by chemical reactions among silica, calcium oxide, alumina and iron oxide.

The traditionally accepted difference between cements and ceramics is thus in how they are initially produced. Objects that go through intense heat treatment for their consolidation are ceramics, while those formed by chemical reaction at room temperature are cements.

THe difference between ceramics and cements, however, goes beyond this definition. From a structural viewpoint, the distinction between ceramics and cements concerns the interparticle bonds that hold them together and provides the necessary strength. Hydraulic cements are bonded by van der waals forces, while ceramics are formed by either ionic or covalent bonds between their particles. Because ionic and covalent bonds are stronger than van der Waals bonds, ceramics have better strength than cements.

Another major distinction between ceramics and hydraulic cements is the porosity. Ceramics are made dense unless their application requires some degree of porosity. Hydraulic cements, however, are inherently porous due to their formation mechanism. micro-pores are fist formed by the hydrogen release which is then followed by the formation of macro-pores and capillaries with the exit of bleed water (that amount of water in excess of what is need for the hydration process) Porosity for good ceramics is
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Executive Editor, Environmental Building News
written by Alex Wilson, July 31, 2010
Great discussion, Bruce and Jonathan. We're working on a feature article on concrete in Environmental Building News (addressing fly ash as well as other developments with cements and concretes), and this information will be very helpful. I found Jonathan's explanations of the contrasting chemical bonds with hydraulic cements and ceramics particularly useful! -Alex
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Interested End User
written by Bob, February 10, 2011
I'm not a Material Scientist (although I did study Engineering), and I'm interested in the use of concrete for building structures. The use of non-'sintered' ceramic, chemically bonded Phosphate cements, incorporating fly-ash is of great potential.
I'm not sure of the differences between these and the so called "Geopolymer" cements, in general terms. Perhaps someone can explain.
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Cellular LIghtweight Concrete Consultant
written by Jesse Thomas, December 18, 2011
Thanks Jonathan for this well written article! Glad to get to track your pioneering works. Just read an article in the Smithsonian and wanted to get your take on their works. Heading to Haiti next month to help build 30 homes thanks to the funding of United Methodists. www.worldhandsalliance.com will be where I post our progress. Cheers! Jesse Thomas

http://www.smithsonianmag.com/science-nature/Building-a-Better-World-With-Green-Cement.html?c=y&page=1

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